Water samples have predominantly been collected by the G-BASE project at an average sampling density of one sample per 1.5 km square. Samples have been collected from approximately 85% of Great Britain but it is only from Wales and Humber-Trent southwards that a wide range of analytes have been determined. Currently G-BASE stream water samples collected from high order streams are determined by ICP-AES for 27 elements - Sr, Cd, Ba, Si, Mn, Fe, P, S (as SO42-), B, Mg, V, Na, Mo, Al, Be, Ca, Zn, Cu, Pb, Li, Zr, Co, Ni, Y, La, K and Cr; and by quadrupole ICP-MS for 24 trace elements - Li, Be, Al, V, Cr, Co, Ni, Cu, As, Rb, Y, Zr, Mo, Ag, Cd, Sn, Sb, Ba, La, Ce, Tl, Pb, Th and U. Automated colorimetric methods are used to determine Cl and NO3- and ion selective electrode is used to determine F. Waters are also analysed for non-purgeable organic carbon (NPOC) to determine dissolved organic carbon content. All samples have routinely been analysed for pH, conductivity and bicarbonate. Much of the UK coverage also includes uranium and fluoride analyses.
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